| Country | Population | Capital |
|---|---|---|
| Algeria | 44,616,624 | Algiers |
| Angola | 33,933,610 | Luanda |
| Benin | 12,451,040 | Porto-Novo |
| Botswana | 2,397,241 | Gaborone |
| Burundi | 12,255,433 | Bujumbura |
| Cameroon | 27,224,265 | Yaounde |
| Central African Republic | 4,919,981 | Bangui |
| Chad | 16,914,985 | N'Djamena |
| Comoros | 888,451 | Moroni |
| Djibouti | 1,002,187 | Djibouti |
| Egypt | 104,258,327 | Cairo |
| Eritrea | 3,601,467 | Asmara |
| eSwatini (Swaziland) | 1,172,362 | Mbabane and Lobamba |
| Ethiopia | 117,876,227 | Addis Ababa |
| Ghana | 31,732,129 | Accra |
| Ivory Coast | 27,053,629 | Yamoussoukro |
| Kenya | 54,985,698 | Nairobi |
| Lesotho | 2,159,079 | Maseru |
| Libya | 6,958,532 | Tripoli |
| Malawi | 19,647,684 | Lilongwe |
| Mauritius | 1,273,433 | Port Louis |
| Morocco | 36,910,560 | Rabat |
| Mozambique | 32,163,047 | Maputo |
| Namibia | 2,587,344 | Windhoek |
| Nigeria | 206,139,589 | Abuja |
| Republic Of The Congo | 5,657,013 | Brazzaville |
| Rwanda | 13,276,513 | Kigali |
| Seychelles | 98,908 | Victoria |
| Somalia | 16,359,504 | Mogadishu |
| South Africa | 59,308,690 | Cape Town (legisl.) Bloemfontein (judicial) Pretoria (admin.) |
| Sudan | 44,909,353 | Khartoum |
| Tanzania | 61,498,437 | Dar es Salaam |
| Togo | 8,478,250 | Lome |
| Tunisia | 11,935,766 | Tunis |
| Uganda | 47,123,531 | Kampala |
| Western Sahara | 611,875 | Laayoune |
| Zambia | 18,920,651 | Lusaka |
| Zimbabwe | 15,092,171 | Harare |
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